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Have you decided to upgrade your site, you need to modify the structure of the site, rename titles and URL identifiers?
Better indexing changes in Google’s help, except sitemap, refurbished and indexed pages over the Fetch as Googlebot (Google’s indexing robot) in Google Webmaster Tools (GWT).
If you are not yet GWT, you can create a new account using the procedure given here.
The classic situation that occurs when renaming URL identifier is that Google will index a 404 – page not found. Before Google understands that you have changed the identifier would take him in the worst case X months and you will lose visitors.